Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes
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Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes
DE PB NW RP
ISBN: 9783659816215 bzw. 3659816213, in Deutsch, LAP Lambert Academic Publishing, Taschenbuch, neu, Nachdruck.
Lieferung aus: Deutschland, Versandkostenfrei.
Von Händler/Antiquariat, AHA-BUCH GmbH [51283250], Einbeck, Germany.
This item is printed on demand - Print on Demand Neuware - This work covers the preparation and structural characterisation of four novel bis(pyrrole-carboxylate) ligands and their polymeric complexes. The synthesis of ligands was based on several synthetic routes. This includes the formation of pyrrole esters that reacted with the diamines precursors to give Schiff-bases. The reduction of Schiff-bases gave the appropriate secondary amine ester compounds, which hydrolised by LiOH to yield the title bis(pyrrole-carboxylate) ligands. The reaction of ligands with some metal ions resulted in the formation of polymeric complexes of the general formula [Cr(Ln)(H2O)2]Cl, [M(Ln)(H2O)4] and Li[Ag(Ln)(H2O)2] (M= Mn(II), Co(II), Ni(II) Cu(II), Zn(II) and Cd(II); Ln= L1-L4). Compounds were fully characterised by elemental analyses, melting points, FTIR, UV-Vis, magnetic susceptibility, NMR spectroscopy (1H-, 13C-, DEPT-13C,-1H-1H COSY and 1H-13C HQMC-NMR), mass spectroscopy, thermal analysis and X-ray single crystal determination. Physico-chemical characterisation indicated the formation of six coordinate structures around metal centre that contain coordinated water molecules and the carboxylato moieties adopt a syn-syn bridging coordination mode. 324 pp. Englisch.
Von Händler/Antiquariat, AHA-BUCH GmbH [51283250], Einbeck, Germany.
This item is printed on demand - Print on Demand Neuware - This work covers the preparation and structural characterisation of four novel bis(pyrrole-carboxylate) ligands and their polymeric complexes. The synthesis of ligands was based on several synthetic routes. This includes the formation of pyrrole esters that reacted with the diamines precursors to give Schiff-bases. The reduction of Schiff-bases gave the appropriate secondary amine ester compounds, which hydrolised by LiOH to yield the title bis(pyrrole-carboxylate) ligands. The reaction of ligands with some metal ions resulted in the formation of polymeric complexes of the general formula [Cr(Ln)(H2O)2]Cl, [M(Ln)(H2O)4] and Li[Ag(Ln)(H2O)2] (M= Mn(II), Co(II), Ni(II) Cu(II), Zn(II) and Cd(II); Ln= L1-L4). Compounds were fully characterised by elemental analyses, melting points, FTIR, UV-Vis, magnetic susceptibility, NMR spectroscopy (1H-, 13C-, DEPT-13C,-1H-1H COSY and 1H-13C HQMC-NMR), mass spectroscopy, thermal analysis and X-ray single crystal determination. Physico-chemical characterisation indicated the formation of six coordinate structures around metal centre that contain coordinated water molecules and the carboxylato moieties adopt a syn-syn bridging coordination mode. 324 pp. Englisch.
2
Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes
DE NW
ISBN: 9783659816215 bzw. 3659816213, in Deutsch, neu.
Lieferung aus: Deutschland, zzgl. Versandkosten.
This work covers the preparation and structural characterisation of four novel bis(pyrrole-carboxylate) ligands and their polymeric complexes. The synthesis of ligands was based on several synthetic routes. This includes the formation of pyrrole esters that reacted with the diamines precursors to give Schiff-bases. The reduction of Schiff-bases gave the appropriate secondary amine ester compounds, which hydrolised by LiOH to yield the title bis(pyrrole-carboxylate) ligands. The reaction of ligands with some metal ions resulted in the formation of polymeric complexes of the general formula [Cr(Ln)(H2O)2]Cl, [M(Ln)(H2O)4] and Li[Ag(Ln)(H2O)2] (M= Mn(II), Co(II), Ni(II) Cu(II), Zn(II) and Cd(II); Ln= L1-L4). Compounds were fully characterised by elemental analyses, melting points, FTIR, UV-Vis, magnetic susceptibility, NMR spectroscopy (1H-, 13C-, DEPT-13C,-1H-1H COSY and 1H-13C HQMC-NMR), mass spectroscopy, thermal analysis and X-ray single crystal determination. Physico-chemical characterisation indicated the formation of six coordinate structures around metal centre that contain coordinated water molecules and the carboxylato moieties adopt a syn-syn bridging coordination mode.
This work covers the preparation and structural characterisation of four novel bis(pyrrole-carboxylate) ligands and their polymeric complexes. The synthesis of ligands was based on several synthetic routes. This includes the formation of pyrrole esters that reacted with the diamines precursors to give Schiff-bases. The reduction of Schiff-bases gave the appropriate secondary amine ester compounds, which hydrolised by LiOH to yield the title bis(pyrrole-carboxylate) ligands. The reaction of ligands with some metal ions resulted in the formation of polymeric complexes of the general formula [Cr(Ln)(H2O)2]Cl, [M(Ln)(H2O)4] and Li[Ag(Ln)(H2O)2] (M= Mn(II), Co(II), Ni(II) Cu(II), Zn(II) and Cd(II); Ln= L1-L4). Compounds were fully characterised by elemental analyses, melting points, FTIR, UV-Vis, magnetic susceptibility, NMR spectroscopy (1H-, 13C-, DEPT-13C,-1H-1H COSY and 1H-13C HQMC-NMR), mass spectroscopy, thermal analysis and X-ray single crystal determination. Physico-chemical characterisation indicated the formation of six coordinate structures around metal centre that contain coordinated water molecules and the carboxylato moieties adopt a syn-syn bridging coordination mode.
3
Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes
~EN NW AB
ISBN: 9783659816215 bzw. 3659816213, vermutlich in Englisch, neu, Hörbuch.
Lieferung aus: Niederlande, Lieferzeit: 5 Tage, zzgl. Versandkosten.
This work covers the preparation and structural characterisation of four novel bis(pyrrole-carboxylate) ligands and their polymeric complexes. The synthesis of ligands was based on several synthetic routes. This includes the formation of pyrrole esters that reacted with the diamines precursors to give Schiff-bases. The reduction of Schiff-bases gave the appropriate secondary amine ester compounds, which hydrolised by LiOH to yield the title bis(pyrrole-carboxylate) ligands. The reaction of ligands with some metal ions resulted in the formation of polymeric complexes of the general formula [Cr(Ln)(H2O)2]Cl, [M(Ln)(H2O)4] and Li[Ag(Ln)(H2O)2] (M= Mn(II), Co(II), Ni(II) Cu(II), Zn(II) and Cd(II), Ln= L1-L4). Compounds were fully characterised by elemental analyses, melting points, FTIR, UV-Vis, magnetic susceptibility, NMR spectroscopy (1H-, 13C-, DEPT-13C,-1H-1H COSY and 1H-13C HQMC-NMR), mass spectroscopy, thermal analysis and X-ray single crystal determination. Physico-chemical characterisation indicated the formation of six coordinate structures around metal centre that contain coordinated water molecules and the carboxylato moieties adopt a syn-syn bridging coordination mode.
This work covers the preparation and structural characterisation of four novel bis(pyrrole-carboxylate) ligands and their polymeric complexes. The synthesis of ligands was based on several synthetic routes. This includes the formation of pyrrole esters that reacted with the diamines precursors to give Schiff-bases. The reduction of Schiff-bases gave the appropriate secondary amine ester compounds, which hydrolised by LiOH to yield the title bis(pyrrole-carboxylate) ligands. The reaction of ligands with some metal ions resulted in the formation of polymeric complexes of the general formula [Cr(Ln)(H2O)2]Cl, [M(Ln)(H2O)4] and Li[Ag(Ln)(H2O)2] (M= Mn(II), Co(II), Ni(II) Cu(II), Zn(II) and Cd(II), Ln= L1-L4). Compounds were fully characterised by elemental analyses, melting points, FTIR, UV-Vis, magnetic susceptibility, NMR spectroscopy (1H-, 13C-, DEPT-13C,-1H-1H COSY and 1H-13C HQMC-NMR), mass spectroscopy, thermal analysis and X-ray single crystal determination. Physico-chemical characterisation indicated the formation of six coordinate structures around metal centre that contain coordinated water molecules and the carboxylato moieties adopt a syn-syn bridging coordination mode.
4
Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes
~EN PB NW
ISBN: 9783659816215 bzw. 3659816213, vermutlich in Englisch, LAP Lambert Academic Publishing, Taschenbuch, neu.
Lieferung aus: Deutschland, Versandkostenfrei.
Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes: This work covers the preparation and structural characterisation of four novel bis(pyrrole-carboxylate) ligands and their polymeric complexes. The synthesis of ligands was based on several synthetic routes. This includes the formation of pyrrole esters that reacted with the diamines precursors to give Schiff-bases. The reduction of Schiff-bases gave the appropriate secondary amine ester compounds, which hydrolised by LiOH to yield the title bis(pyrrole-carboxylate) ligands. The reaction of ligands with some metal ions resulted in the formation of polymeric complexes of the general formula [Cr(Ln)(H2O)2]Cl, [M(Ln)(H2O)4] and Li[Ag(Ln)(H2O)2] (M= Mn(II), Co(II), Ni(II) Cu(II), Zn(II) and Cd(II) Ln= L1-L4). Compounds were fully characterised by elemental analyses, melting points, FTIR, UV-Vis, magnetic susceptibility, NMR spectroscopy (1H-, 13C-, DEPT-13C,-1H-1H COSY and 1H-13C HQMC-NMR), mass spectroscopy, thermal analysis and X-ray single crystal determination. Physico-chemical characterisation indicated the formation of six coordinate structures around metal centre that contain coordinated water molecules and the carboxylato moieties adopt a syn-syn bridging coordination mode. Englisch, Taschenbuch.
Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes: This work covers the preparation and structural characterisation of four novel bis(pyrrole-carboxylate) ligands and their polymeric complexes. The synthesis of ligands was based on several synthetic routes. This includes the formation of pyrrole esters that reacted with the diamines precursors to give Schiff-bases. The reduction of Schiff-bases gave the appropriate secondary amine ester compounds, which hydrolised by LiOH to yield the title bis(pyrrole-carboxylate) ligands. The reaction of ligands with some metal ions resulted in the formation of polymeric complexes of the general formula [Cr(Ln)(H2O)2]Cl, [M(Ln)(H2O)4] and Li[Ag(Ln)(H2O)2] (M= Mn(II), Co(II), Ni(II) Cu(II), Zn(II) and Cd(II) Ln= L1-L4). Compounds were fully characterised by elemental analyses, melting points, FTIR, UV-Vis, magnetic susceptibility, NMR spectroscopy (1H-, 13C-, DEPT-13C,-1H-1H COSY and 1H-13C HQMC-NMR), mass spectroscopy, thermal analysis and X-ray single crystal determination. Physico-chemical characterisation indicated the formation of six coordinate structures around metal centre that contain coordinated water molecules and the carboxylato moieties adopt a syn-syn bridging coordination mode. Englisch, Taschenbuch.
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Symbolbild
Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes (2016)
DE PB NW RP
ISBN: 9783659816215 bzw. 3659816213, in Deutsch, Lap Lambert Academic Publishing, Taschenbuch, neu, Nachdruck.
Von Händler/Antiquariat, English-Book-Service Mannheim [1048135], Mannheim, Germany.
This item is printed on demand for shipment within 3 working days.
This item is printed on demand for shipment within 3 working days.
6
Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes
~EN PB NW
ISBN: 3659816213 bzw. 9783659816215, vermutlich in Englisch, LAP Lambert Academic Publishing, Taschenbuch, neu.
Die Beschreibung dieses Angebotes ist von geringer Qualität oder in einer Fremdsprache. Trotzdem anzeigen
7
Synthesis of Bis(pyrrole-carboxylate) Polymeric Complexes (2016)
~EN PB NW
ISBN: 9783659816215 bzw. 3659816213, vermutlich in Englisch, Taschenbuch, neu.
Lieferung aus: Deutschland, Next Day, Versandkostenfrei.
Die Beschreibung dieses Angebotes ist von geringer Qualität oder in einer Fremdsprache. Trotzdem anzeigen
Die Beschreibung dieses Angebotes ist von geringer Qualität oder in einer Fremdsprache. Trotzdem anzeigen
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