Electrochemistry of Solids: An Introduction (Inorganic Chemistry Concepts)
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Von Händler/Antiquariat, AHA-BUCH GmbH [51283250], Einbeck, NDS, Germany.
This item is printed on demand - Print on Demand Titel. Neuware - 1 Introduction.- 1.1 References.- 2 Disorder in Solids.- 2.1 General Considerations Regarding Lattice Defects and Their Significance.- 2.2 Point Defects.- 2.3 Disorder Equilibria.- 2.4 The Chemical Potentials of Defects.- 2.5 Internal Disorder Equilibria.- 2.6 Kinetic Derivation of Disorder Equilibria.- 2.7 Disorder Equilibria Involving Neighbouring Phases.- 2.8 Disorder Equilibria Involving Surfaces.- 2.9 References.- 3 Examples of Bisorder in Solids.- 3.1 Disorder in Doped Zirconium Dioxide and Thorium Dioxide.- 3.2 Disorder in ZnO, Cu2O and CuO.- 3.3 Structural Disorder.- 3.4 References.- 4 Thermodynamie Quantities of Quasi-Free Electrons and Electron Defects in Semiconductors.- 4.1 General Considerations.- 4.2 Electrochemical Potential $$ildeeta_{m e}$$ of Electrons.- 4.3 The Fermi Distribution Function f ( ).- 4.4 The Density of States D( ).- 4.5 Relation Between the Concentration of Electrons or Electron Defects and Their Electrochemical Potential.- 4.6 Chemical Potential of Electrons and Standard States.- 4.7 The Activity Coefficient of Electrons and Electron Defects in the Case of Degeneracy.- 4.8 The Phase Boundary Solid/Vacuum. The Work Function W.- 4.9 The Volta Potential or Contact Potential.- 4.10 The Phase Boundary Solid I/Solid II. The Galvani Voltage.- 4.11 References.- 5 An Example of Electronic Disorder. Electrons and Electron Defects in -Ag2S.- 5.1 Disorder in -Ag2S and Coulometric Titration Curve.- 5.2 Quantitative Evaluation of Coulometric Titration Curves of -Ag2S.- 5.3 Entropy and Enthalpy of the Electrons in Ag2S.- 5.4 References.- 6 Mobility, Diffusion and Partial Conductivity of Ions and Electrons.- 6.1 Phenomenological Treatment of Transport Processes.- 6.1.1 Diffusion Equations.- 6.1.2 The Mechanical Mobility Bm.- 6.1.3 The Nernst-Einstein Equation.- 6.1.4 The Component Diffusion Coefficient DK.- 6.1.5 Relationship Between D and DK.- 6.1.6 Relationship Between the Component Diffusion Coefficient DK and the Tracer Diffusion Coefficient DTr.- 6.1.7 Particle Flux in an Electrical Field.- 6.1.8 Particle Flux in the Presence of a Concentration or Activity Gradient and an Electrical Field.- 6.1.9 Description of Particle Fluxes Using the General Transport Equations of Irreversible Thermodynamics.- 6.1.10 Chemical Diffusion.- 6.2 Statistical Treatment of Transport Quantities.- 6.3 Experimental Determination of Partial Conductivities.- 6.3.1 Transference Measurements.- 6.3.2 Measurements of Transference Numbers by Means of Emf Measurements Using Galvanic Cells.- 6.3.3 Determination of Partial Conductivities by Means of Stationary Polarization Measurements.- 6.4 Alternating Current Measurements. Complex Impedance Diagrams.- 6.5 References.- 7 Solid Ionic Conductors, Solid Electrolytes and Solid-Solution Electrodes.- 7.1 Solid Ionic Conductors, Solid Electrolytes.- 7.1.1 Oxygen Ion Conductors.- 7.1.2 Sodium Ion Conductors.- 7.1.3 Silver Ion Conductors.- 7.1.4 Copper Ion Conductors.- 7.1.5 Lithium Ion Conductors.- 7.1.6 Fluorine Ion Conductors.- 7.2 Solid-Solution Electrodes.- 7.3 References.- 8 Galvanic Cells with Solid Electrolytes for Thermodynamic Investigations.- 8.1 Determination of Gibbs Reaction Energies.- 8.2 Determination of Chemical Potentials, Thermodynamic Activities or Partial Pressures.- 8.2.1 Galvanic Cells of the First Kind.- 8.2.2 Galvanic Cells of the Second Kind.- 8.3 Determination of S and H from the Temperature-Dependence of the Electromotive Force of Galvanic Cells.- 8.4 References.- 9 Technical Applications of Solid Electrolytes -Solid-State Ionics.- 9.1 Sensors.- 9.2 Fuel Cells and Electrolyzers.- 9.3 Batteries with Solid Electrolytes. The Sodium-Sulfur Battery.- 9.4 Chemotronic Building Units.- 9.4.1 Coulometers and Time Switches.- 9.4.2 Analog Memories.- 9.4.3 Capacitors Containing Solid Electrolytes.- 9.5 References.- 10 Solid-State Reactions.- 10.1 Theory of the Formation of Tarnishing Layers on Metal Surfaces.- 10.1.

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Electrochemistry-of-Solids~~Hans-Rickert, Electrochemistry of Solids: An Introduction, Hardcover.

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